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Strain-Induced Regioselective Ring-Opening Cross-Metathesis of Hybrid Cage Propellane Containing both Bicyclo[2.2.1]heptene and Bicyclo[2.2.2]octene Units
Journal
Synlett
ISSN
09365214
Date Issued
2022-06-20
Author(s)
Kotha, Sambasivarao
Mehta, Gulazarahind
Abstract
Herein, we report strain-driven regioselective tandem ringopening cross-metathesis (ROCM) of a linearly fused cage system that contains both bicyclo[2.2.1]heptene and bicyclo[2.2.2]octene units fused to the same cage system. The synthesis of novel cage propellane involves Diels-Alder cycloaddition and [2+2] photocycloaddition as key steps.
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